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Selective acceleration of disfavored enolate addition reactions by anion–π interactions

In chemistry and biology, cation–π interactions contribute significantly to many important transformations. In sharp contrast, reactions accomplished with support from the complementary anion–π interactions are essentially unknown. In this report, we show that anion–π interactions can determine the...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Zhao, Yingjie, Benz, Sebastian, Sakai, Naomi, Matile, Stefan
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054047/
https://ncbi.nlm.nih.gov/pubmed/30090238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02563j
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