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Mechanism for Fluorescence Quenching of Tryptophan by Oxamate and Pyruvate: Conjugation and Solvation-Induced Photoinduced Electron Transfer
Oxamate and pyruvate are isoelectronic molecules. They both quench tryptophan fluorescence with Stern–Volmer constants of 16 and 20 M(−1), respectively, which are comparable to that of arcrylamide, a commonly used probe for protein structure. On the other hand, it is well known that neither the carb...
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| Veröffentlicht in: | J Phys Chem B |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6038119/ https://ncbi.nlm.nih.gov/pubmed/29860828 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.8b02433 |
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