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Mechanism for Fluorescence Quenching of Tryptophan by Oxamate and Pyruvate: Conjugation and Solvation-Induced Photoinduced Electron Transfer

Oxamate and pyruvate are isoelectronic molecules. They both quench tryptophan fluorescence with Stern–Volmer constants of 16 and 20 M(−1), respectively, which are comparable to that of arcrylamide, a commonly used probe for protein structure. On the other hand, it is well known that neither the carb...

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Detalhes bibliográficos
Publicado no:J Phys Chem B
Main Authors: Peng, Huo-Lei, Callender, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6038119/
https://ncbi.nlm.nih.gov/pubmed/29860828
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.8b02433
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