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Fast Hydrogen Atom Abstraction by a Hydroxo Iron(III) Porphyrazine
A reactive hydroxoferric porphyrazine complex, [(PyPz)Fe(III)(OH) (OH(2))](4+) (1, PyPz = tetramethyl-2,3-pyridino porphyrazine), has been prepared via one-electron oxidation of the corresponding ferrous species [(PyPz)Fe(II)(OH(2))(2)](4+) (2). Electrochemical analysis revealed a pH-dependent and r...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6036922/ https://ncbi.nlm.nih.gov/pubmed/28245648 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13091 |
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