An Artificial Heme Enzyme for Cyclopropanation Reactions

An artificial heme enzyme was created through self‐assembly from hemin and the lactococcal multidrug resistance regulator (LmrR). The crystal structure shows the heme bound inside the hydrophobic pore of the protein, where it appears inaccessible for substrates. However, good catalytic activity and...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Villarino, Lara, Splan, Kathryn E., Reddem, Eswar, Alonso‐Cotchico, Lur, Gutiérrez de Souza, Cora, Lledós, Agustí, Maréchal, Jean‐Didier, Thunnissen, Andy‐Mark W. H., Roelfes, Gerard
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2018
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6033091/
https://ncbi.nlm.nih.gov/pubmed/29719099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802946
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