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Asymmetric Reductive Carbocyclization Using Engineered Ene Reductases

Ene reductases from the Old Yellow Enzyme (OYE) family reduce the C=C double bond in α,β‐unsaturated compounds bearing an electron‐withdrawing group, for example, a carbonyl group. This asymmetric reduction has been exploited for biocatalysis. Going beyond its canonical function, we show that member...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Heckenbichler, Kathrin, Schweiger, Anna, Brandner, Lea Alexandra, Binter, Alexandra, Toplak, Marina, Macheroux, Peter, Gruber, Karl, Breinbauer, Rolf
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6033016/
https://ncbi.nlm.nih.gov/pubmed/29689601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802962
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