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Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes

Despite the critical role ruthenium and osmium complexes have played in the development of transition metal dinitrogen chemistry, they have not been previously shown to mediate catalytic N(2)-to-NH(3) conversion (N(2)RR), nor have M-N(x)H(y) complexes been derived from protonation of M-N(2) precurso...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Fajardo, Javier, Peters, Jonas C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6019285/
https://ncbi.nlm.nih.gov/pubmed/29073760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10204
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