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Enantioselective Palladium-Catalyzed Allylic Alkylation Reactions in the Synthesis of Aspidosperma and Structurally Related Monoterpene Indole Alkaloids

Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperm...

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Bibliografiske detaljer
Udgivet i:Nat Prod Rep
Main Authors: Pritchett, Beau P., Stoltz, Brian M.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6013405/
https://ncbi.nlm.nih.gov/pubmed/29658039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7np00069c
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