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Synthesis of Unsymmetrical 2,6-Diarylanilines by Palladium-Catalyzed C–H Bond Functionalization Methodology
3,5-Dimethylpyrazole was employed as a mono-dentate directing group for palladium-catalyzed ortho-sp(2) C–H arylation with aryl iodides. The reaction shows good functional group tolerance and outstanding selectivity for mono-ortho-arylation. Ozonolysis of ortho-arylated arylpyrazoles gave acylated b...
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| Udgivet i: | J Org Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6013069/ https://ncbi.nlm.nih.gov/pubmed/29737848 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00659 |
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