Загрузка...
Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity
We report the first catalytic methods for the transformation of C–H bonds of unactivated arenes into C–Al bonds. The catalytic reactions occur at 25 °C (benzene, toluene and xylenes) with palladium loadings as low as 0.1 mol%. Remarkably, the C–H activation of toluene and xylenes proceeds with ortho...
Сохранить в:
| Опубликовано в: : | Chem Sci |
|---|---|
| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2018
|
| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6011207/ https://ncbi.nlm.nih.gov/pubmed/30155233 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02072h |
| Метки: |
Добавить метку
Нет меток, Требуется 1-ая метка записи!
|