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Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity

We report the first catalytic methods for the transformation of C–H bonds of unactivated arenes into C–Al bonds. The catalytic reactions occur at 25 °C (benzene, toluene and xylenes) with palladium loadings as low as 0.1 mol%. Remarkably, the C–H activation of toluene and xylenes proceeds with ortho...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Hooper, Thomas N., Garçon, Martí, White, Andrew J. P., Crimmin, Mark R.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6011207/
https://ncbi.nlm.nih.gov/pubmed/30155233
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02072h
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