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Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity
We report the first catalytic methods for the transformation of C–H bonds of unactivated arenes into C–Al bonds. The catalytic reactions occur at 25 °C (benzene, toluene and xylenes) with palladium loadings as low as 0.1 mol%. Remarkably, the C–H activation of toluene and xylenes proceeds with ortho...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6011207/ https://ncbi.nlm.nih.gov/pubmed/30155233 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02072h |
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