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The Raman fingerprint of cyclic conjugation: the case of the stabilization of cations and dications in cycloparaphenylenes
Radical cations and dications of [n]CPP from n = 5 to n = 12 have been studied by Raman spectroscopy and density functional theory. Small [n]CPP dications owe their stability to the closed-shell electronic structure imposed by cyclic conjugation surpassing the destabilizing effect of ring strain and...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6007183/ https://ncbi.nlm.nih.gov/pubmed/29997841 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00765a |
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