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Stretching [8]cycloparaphenylene with encapsulated potassium cations: structural and theoretical insights into core perturbation upon four-fold reduction and complexation
The consequences of four-electron addition to [8]cycloparaphenylene ([8]CPP, 1) have been evaluated crystallographically, revealing a significant core deformation. The structural analysis exposes an elliptical distortion observed upon electron transfer, with the deformation parameter (D.P.) increase...
Gorde:
| Argitaratua izan da: | Chem Sci |
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| Egile Nagusiak: | , , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
The Royal Society of Chemistry
2021
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8132928/ https://ncbi.nlm.nih.gov/pubmed/34040728 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00713k |
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