Stretching [8]cycloparaphenylene with encapsulated potassium cations: structural and theoretical insights into core perturbation upon four-fold reduction and complexation

The consequences of four-electron addition to [8]cycloparaphenylene ([8]CPP, 1) have been evaluated crystallographically, revealing a significant core deformation. The structural analysis exposes an elliptical distortion observed upon electron transfer, with the deformation parameter (D.P.) increase...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Rogachev, Andrey Yu., Zhou, Zheng, Liu, Shuyang, Wei, Zheng, Schaub, Tobias A., Jasti, Ramesh, Petrukhina, Marina A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society of Chemistry 2021
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8132928/
https://ncbi.nlm.nih.gov/pubmed/34040728
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00713k
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