Stable luminescent iridium(iii) complexes with bis(N-heterocyclic carbene) ligands: photo-stability, excited state properties, visible-light-driven radical cyclization and CO(2) reduction, and cellular imaging

A new class of cyclometalated Ir(iii) complexes supported by various bidentate C-deprotonated (C^N) and cis-chelating bis(N-heterocyclic carbene) (bis-NHC) ligands has been synthesized. These complexes display strong emission in deaerated solutions at room temperature with photoluminescence quantum...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yang, Chen, Mehmood, Faisal, Lam, Tsz Lung, Chan, Sharon Lai-Fung, Wu, Yuan, Yeung, Chi-Shun, Guan, Xiangguo, Li, Kai, Chung, Clive Yik-Sham, Zhou, Cong-Ying, Zou, Taotao, Che, Chi-Ming
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003676/
https://ncbi.nlm.nih.gov/pubmed/29997803
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04458h
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