Iridium(III) Hydrido N-Heterocyclic Carbene–Phosphine Complexes as Catalysts in Magnetization Transfer Reactions

[Image: see text] The hyperpolarization (HP) method signal amplification by reversible exchange (SABRE) uses para-hydrogen to sensitize substrate detection by NMR. The catalyst systems [Ir(H)(2)(IMes)(MeCN)(2)(R)]BF(4) and [Ir(H)(2)(IMes)(py)(2)(R)]BF(4) [py = pyridine; R = PCy(3) or PPh(3); IMes =...

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Detalhes bibliográficos
Main Authors: Fekete, Marianna, Bayfield, Oliver, Duckett, Simon B., Hart, Sam, Mewis, Ryan E., Pridmore, Natalie, Rayner, Peter J., Whitwood, Adrian
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3850244/
https://ncbi.nlm.nih.gov/pubmed/24215616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic401783c
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