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Iridium Cyclooctene Complex That Forms a Hyperpolarization Transfer Catalyst before Converting to a Binuclear C–H Bond Activation Product Responsible for Hydrogen Isotope Exchange
[Image: see text] [IrCl(COE)(2)](2) (1) reacts with pyridine (py) and H(2) to form crystallographically characterized IrCl(H)(2)(COE)(py)(2) (2). 2 undergoes py loss to form 16-electron IrCl(H)(2)(COE)(py) (3), with equivalent hydride ligands. When this reaction is studied with parahydrogen, 1 effic...
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| 出版年: | Inorg Chem |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical Society
2016
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5193467/ https://ncbi.nlm.nih.gov/pubmed/27934314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02560 |
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