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Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen
We report the formation of a series of novel [Ir(H)(2)(IMes)(α-(13)C(2)-carboxyimine)L] complexes in which the identity of the coligand L is varied. When examined with para-hydrogen, complexes in which L is benzylamine or phenethylamine show significant (1)H hydride and (13)C(2) imine enhancements a...
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| Publicado no: | Chem Sci |
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| Principais autores: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6540910/ https://ncbi.nlm.nih.gov/pubmed/31191878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00444k |
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