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Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe(3))(CH(2)Cl(2))][BAr(F)(4)] precatalyst: stoichiometric and catalytic studies
We report a detailed, combined experimental and computational study on the fundamental B–H and P–H bond activation steps involved in the dehydrocoupling/dehydropolymerization of primary and secondary phosphine–boranes, H(3)B·PPhR′H (R = Ph, H), using [RhCp*(PMe(3))Me(ClCH(2)Cl)][BAr(F)(4)], to eithe...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6003611/ https://ncbi.nlm.nih.gov/pubmed/29997783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04150c |
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