Copper-Catalyzed Chan–Lam Cyclopropylation of Phenols and Azaheterocycles

Small molecules containing cyclopropane–heteroatom linkages are commonly needed in medicinal chemistry campaigns, yet are problematic to prepare using existing methods. To address this issue, a scalable Chan–Lam cyclopropylation reaction using potassium cyclopropyl trifluoroborate has been developed...

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發表在:J Org Chem
Main Authors: Derosa, Joseph, O’Duill, Miriam, Holcomb, Matthew, Boulous, Mark N., Patman, Ryan L., Wang, Fen, Tran-Dubé, Michelle, McAlpine, Indrawan, Engle, Keary M.
格式: Artigo
語言:Inglês
出版: 2018
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Article
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003411/
https://ncbi.nlm.nih.gov/pubmed/29498847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b03100
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