Cu-Catalyzed Hydroboration of Benzylidenecyclopropanes: Reaction Optimization, (Hetero)Aryl Scope, and Origins of Pathway Selectivity

The copper-catalyzed hydroboration of benzylidenecyclopropanes, conveniently accessed in one step from readily available benzaldehydes, is reported. Under otherwise identical reaction conditions, two distinct phosphine ligands grant access to different products by either suppressing or promoting cyc...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Medina, Jose M., Kang, Taeho, Erbay, Tuğçe G., Shao, Huiling, Gallego, Gary M., Yang, Shouliang, Tran-Dubé, Michelle, Richardson, Paul F., Derosa, Joseph, Helsel, Ryan T., Patman, Ryan L., Wang, Fen, Ashcroft, Christopher P., Braganza, John F., McAlpine, Indrawan, Liu, Peng, Engle, Keary M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7331956/
https://ncbi.nlm.nih.gov/pubmed/32617185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b03557
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