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Catalytic Carbo- and Aminoboration of Alkenyl Carbonyl Compounds via 5- and 6-Membered Palladacycles
A palladium(II)-catalyzed alkene difunctionalization reaction has been developed, wherein B(2)pin(2) is used to trap chelation-stabilized alkylpalladium(II) intermediates that are formed upon nucleopalladation. A range of carbon and nitrogen nucleophiles were found to be suitable coupling partners i...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6002770/ https://ncbi.nlm.nih.gov/pubmed/29384373 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00881 |
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