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Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds
A nickel-catalyzed conjunctive cross-coupling of non-conjugated alkenes, alkyl halides, and alkylzinc reagents is reported. Regioselectivity is controlled by chelation of a removable bidentate 8-aminoquinoline directing group. Under optimized conditions, a wide range of 1,2-dialkylated products can...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6001383/ https://ncbi.nlm.nih.gov/pubmed/29997883 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01735b |
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