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Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

Removable tridentate directing groups inspired by pincer ligands have been designed to stabilize otherwise kinetically and thermodynamically disfavored 6-membered alkyl palladacycle intermediates. This family of directing groups enables regioselective remote hydrocarbofunctionalization of several sy...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: O’Duill, Miriam L., Matsuura, Rei, Wang, Yanyan, Turnbull, Joshua L., Gurak, John A., Gao, De-Wei, Lu, Gang, Liu, Peng, Engle, Keary M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6002750/
https://ncbi.nlm.nih.gov/pubmed/28972751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08383
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