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Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

Removable tridentate directing groups inspired by pincer ligands have been designed to stabilize otherwise kinetically and thermodynamically disfavored 6-membered alkyl palladacycle intermediates. This family of directing groups enables regioselective remote hydrocarbofunctionalization of several sy...

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Bibliographische Detailangaben
Veröffentlicht in:J Am Chem Soc
Hauptverfasser: O’Duill, Miriam L., Matsuura, Rei, Wang, Yanyan, Turnbull, Joshua L., Gurak, John A., Gao, De-Wei, Lu, Gang, Liu, Peng, Engle, Keary M.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2017
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6002750/
https://ncbi.nlm.nih.gov/pubmed/28972751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08383
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