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Desymmetrization of meso-Dibromocycloalkenes through Copper(I)-Catalyzed Asymmetric Allylic Substitution with Organolithium Reagents
[Image: see text] The highly regio- and enantioselective (up to >99:1 dr, up to 99:1 er) desymmetrization of meso-1,4-dibromocycloalk-2-enes using asymmetric allylic substitution with organolithium reagents to afford enantioenriched bromocycloalkenes (ring size of 5 to 7) has been achieved. The c...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2018
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6002767/ https://ncbi.nlm.nih.gov/pubmed/29790736 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b02992 |
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