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Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates
Allenylsilanolates can undergo cross-coupling at the α- or γ-terminus, and site selectivity appears to be determined by the intrinsic transmetalation mechanism. Fine-tuning of concentration, nucleophilicity, and steric bulk of the silanolate moiety allows for the selective formation of one isomer ov...
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| Gepubliceerd in: | Synlett |
|---|---|
| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2017
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5997285/ https://ncbi.nlm.nih.gov/pubmed/29904234 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0036-1588471 |
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