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Mechanistic Significance of the Si–O–Pd Bond in the Palladium-Catalyzed Cross-Coupling Reactions of Alkenylsilanolates
[Image: see text] Through the combination of reaction kinetics (both catalytic and stoichiometric) and solid-state characterization of arylpalladium(II) alkenylsilanolate complexes, the intermediacy of covalent adducts containing Si–O–Pd linkages in the cross-coupling reactions of organosilanolates...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical
Society
2015
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4442670/ https://ncbi.nlm.nih.gov/pubmed/25945390 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02515 |
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