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Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates
Allenylsilanolates can undergo cross-coupling at the α- or γ-terminus, and site selectivity appears to be determined by the intrinsic transmetalation mechanism. Fine-tuning of concentration, nucleophilicity, and steric bulk of the silanolate moiety allows for the selective formation of one isomer ov...
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| Publicado en: | Synlett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5997285/ https://ncbi.nlm.nih.gov/pubmed/29904234 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0036-1588471 |
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