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Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C–H borylation catalysts

While the dearomatization of indoles by carbon–boron bond forming reactions is new and quite promising, they are so far mainly metal-catalyzed. Here, we establish the use of metal-free catalysts in promoting such reactions in an atom-efficient way. The in situ generated ambiphilic aminoborane cataly...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Jayaraman, Arumugam, Misal Castro, Luis C., Desrosiers, Vincent, Fontaine, Frédéric-Georges
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5994747/
https://ncbi.nlm.nih.gov/pubmed/29938036
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01093e
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