Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes

Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...

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Vydáno v:Chem Sci
Hlavní autoři: Li, Hongbo, Guo, Huifang, Li, Zhiwen, Wu, Cai, Li, Jing, Zhao, Chunliang, Guo, Shuangxi, Ding, Yi, He, Wei, Li, Yadong
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5982200/
https://ncbi.nlm.nih.gov/pubmed/29910932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01427b
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