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Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes
Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5982200/ https://ncbi.nlm.nih.gov/pubmed/29910932 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01427b |
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