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Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes

Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...

Täydet tiedot

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Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Li, Hongbo, Guo, Huifang, Li, Zhiwen, Wu, Cai, Li, Jing, Zhao, Chunliang, Guo, Shuangxi, Ding, Yi, He, Wei, Li, Yadong
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Royal Society of Chemistry 2018
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC5982200/
https://ncbi.nlm.nih.gov/pubmed/29910932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01427b
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