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Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes
Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5982200/ https://ncbi.nlm.nih.gov/pubmed/29910932 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01427b |
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