Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes

Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...

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Foilsithe in:Chem Sci
Main Authors: Li, Hongbo, Guo, Huifang, Li, Zhiwen, Wu, Cai, Li, Jing, Zhao, Chunliang, Guo, Shuangxi, Ding, Yi, He, Wei, Li, Yadong
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2018
Ábhair:
Chemistry
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5982200/
https://ncbi.nlm.nih.gov/pubmed/29910932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01427b
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