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Gold-Catalyzed Intramolecular Allylation of Silyl Alkynes Induced by Silane Alcoholysis
[Image: see text] The activation of alkynyl allyl silanes with cationic gold catalyst in the presence of alcohols provides a vinyl silanes that contain the allyl group at the β-position and the alkoxysilyl group in cis-orientation. The bond reorganization processe is most consistent with the involve...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2569199/ https://ncbi.nlm.nih.gov/pubmed/16910645 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja062560p |
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