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Supramolecular trap for a transient corannulene trianion

The first structural characterization of the transient triply-reduced state of corannulene (C(20)H(10)) is accomplished. The X-ray crystallographic study reveals that the C(20)H(10)˙(3–) trianions, generated by corannulene reduction with metallic cesium, form a novel type of supramolecular sandwich-...

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Publicat a:Chem Sci
Autors principals: Zabula, Alexander V., Spisak, Sarah N., Filatov, Alexander S., Rogachev, Andrey Yu., Clérac, Rodolphe, Petrukhina, Marina A.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5966907/
https://ncbi.nlm.nih.gov/pubmed/29899919
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04385a
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