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Self-assembly of tetrareduced corannulene with mixed Li–Rb clusters: dynamic transformations, unique structures and record (7)Li NMR shifts

Self-assembly processes of the highly reduced bowl-shaped corannulene generated by the chemical reduction with a binary combination of alkali metals, namely Li–Rb, have been investigated by variable-temperature (1)H and (7)Li NMR spectroscopy. The formation of several unique mixed metal sandwich pro...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Filatov, Alexander S., Spisak, Sarah N., Zabula, Alexander V., McNeely, James, Rogachev, Andrey Yu., Petrukhina, Marina A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5496504/
https://ncbi.nlm.nih.gov/pubmed/28717455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03485f
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