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Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom such as oxygen atom and nitrogen atom. By contrast, to achieve hydroformylation on the β position of the heteroatom is a tough task. Herein, we report the asymmetric rhodium-catalyzed hydroform...

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Detalles Bibliográficos
Publicado en:Nat Commun
Main Authors: You, Cai, Li, Xiuxiu, Yang, Yuhong, Yang, Yu-Sheng, Tan, Xuefeng, Li, Shuailong, Wei, Biao, Lv, Hui, Chung, Lung-Wa, Zhang, Xumu
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group UK 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5966446/
https://ncbi.nlm.nih.gov/pubmed/29795178
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-04277-7
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