Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization

A series of 37 dinitroxide biradicals have been prepared and their performance studied as polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1,1,2,2-tetrachloroethane (TCE). We observe that in this regime the DNP performance is strongly correlated with the substituents on th...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Kubicki, Dominik J., Casano, Gilles, Schwarzwälder, Martin, Abel, Sébastien, Sauvée, Claire, Ganesan, Karthikeyan, Yulikov, Maxim, Rossini, Aaron J., Jeschke, Gunnar, Copéret, Christophe, Lesage, Anne, Tordo, Paul, Ouari, Olivier, Emsley, Lyndon
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2016
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952883/
https://ncbi.nlm.nih.gov/pubmed/29896347
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02921j
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