Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization

A series of 37 dinitroxide biradicals have been prepared and their performance studied as polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1,1,2,2-tetrachloroethane (TCE). We observe that in this regime the DNP performance is strongly correlated with the substituents on th...

Ful tanımlama

Kaydedildi:
Detaylı Bibliyografya
Yayımlandı:Chem Sci
Asıl Yazarlar: Kubicki, Dominik J., Casano, Gilles, Schwarzwälder, Martin, Abel, Sébastien, Sauvée, Claire, Ganesan, Karthikeyan, Yulikov, Maxim, Rossini, Aaron J., Jeschke, Gunnar, Copéret, Christophe, Lesage, Anne, Tordo, Paul, Ouari, Olivier, Emsley, Lyndon
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: Royal Society of Chemistry 2016
Konular:
Chemistry
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952883/
https://ncbi.nlm.nih.gov/pubmed/29896347
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02921j
Etiketler: Etiketle
Etiket eklenmemiş, İlk siz ekleyin!

Benzer Materyaller