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Rhodium-catalyzed regioselective addition of the ortho C–H bond in aromatic amides to the C–C double bond in α,β-unsaturated γ-lactones and dihydrofurans

An unprecedented C–H alkylation using α,β-unsaturated γ-lactones (butenolides) and dihydrofurans was achieved by the Rh-catalyzed reaction of benzamides. C–C bond formation occurs between the ortho-position of the benzamide derivative and the γ-position of the butenolide or the α-position of the dih...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Shibata, Kaname, Chatani, Naoto
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952307/
https://ncbi.nlm.nih.gov/pubmed/29861979
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03110a
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