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Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals
[Image: see text] Au(I) in combination with AgOTf enables the unprecedented direct and α-stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of the enol ether glycoside. The room...
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| Izdano u: | J Am Chem Soc |
|---|---|
| Glavni autori: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical
Society
2017
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| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5951607/ https://ncbi.nlm.nih.gov/pubmed/28934850 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08898 |
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