Water oxidation catalysed by iron complex of N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron–oxo intermediates and density functional theory calculations

The macrocyclic [Fe(III)(L1)Cl(2)](+) (1, L1 = N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane) complex is an active catalyst for the oxidation of water to oxygen using [NH(4)](2)[Ce(IV)(NO(3))(6)] (CAN), NaIO(4), or Oxone as the oxidant. The mechanism of 1-catalysed water oxidation was examined by...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: To, Wai-Pong, Wai-Shan Chow, Toby, Tse, Chun-Wai, Guan, Xiangguo, Huang, Jie-Sheng, Che, Chi-Ming
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2015
Pynciau:
Chemistry
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5950833/
https://ncbi.nlm.nih.gov/pubmed/29861914
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01680k
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