Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds

The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes caused the formation of spirocyclic germanes, which is postulated to occur by double acetylene insertion into germylene attached bonds. Further insertion of the formed cyclic divinylgermylene into transannular Si...

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Bibliographic Details
Published in:Dalton Trans
Main Authors: Walewska, Małgorzata, Baumgartner, Judith, Marschner, Christoph, Albers, Lena, Müller, Thomas
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2018
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5946683/
https://ncbi.nlm.nih.gov/pubmed/29658036
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt00315g
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