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1,2- and 1,1-Migratory Insertion Reactions of Silylated Germylene Adducts

The reactions of the PMe(3) adduct of the silylated germylene [(Me(3)Si)(3)Si](2)Ge: with GeCl(2)·dioxane were found to yield 1,1-migratory insertion products of GeCl(2) into one or two Ge–Si bonds. In a related reaction, a germylene was inserted with tris(trimethylsilyl)silyl and vinyl substituents...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Walewska, Małgorzata, Baumgartner, Judith, Marschner, Christoph
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7037258/
https://ncbi.nlm.nih.gov/pubmed/32041130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25030686
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