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Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds

The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes caused the formation of spirocyclic germanes, which is postulated to occur by double acetylene insertion into germylene attached bonds. Further insertion of the formed cyclic divinylgermylene into transannular Si...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Walewska, Małgorzata, Baumgartner, Judith, Marschner, Christoph, Albers, Lena, Müller, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5946683/
https://ncbi.nlm.nih.gov/pubmed/29658036
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt00315g
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