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Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds
The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes caused the formation of spirocyclic germanes, which is postulated to occur by double acetylene insertion into germylene attached bonds. Further insertion of the formed cyclic divinylgermylene into transannular Si...
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| 發表在: | Dalton Trans |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5946683/ https://ncbi.nlm.nih.gov/pubmed/29658036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt00315g |
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