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Directed β C–H Amination of Alcohols via Radical Relay Chaperones
A radical-mediated strategy for β C–H amination of alcohols has been developed. This approach employs a radical relay chaperone, which serves as a traceless director that facilitates selective C–H functionalization via 1,5-hydrogen atom transfer (HAT) and enables net incorporation of ammonia at the...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5940001/ https://ncbi.nlm.nih.gov/pubmed/28741940 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05214 |
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