Structural characterization of a non-heme iron active site in zeolites that hydroxylates methane

Iron-containing zeolites exhibit unprecedented reactivity in the low-temperature hydroxylation of methane to form methanol. Reactivity occurs at a mononuclear ferrous active site, α-Fe(II), that is activated by N(2)O to form the reactive intermediate α-O. This has been defined as an Fe(IV)=O species...

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Bibliografische gegevens
Gepubliceerd in:Proc Natl Acad Sci U S A
Hoofdauteurs: Snyder, Benjamin E. R., Böttger, Lars H., Bols, Max L., Yan, James J., Rhoda, Hannah M., Jacobs, Ariel B., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: National Academy of Sciences 2018
Onderwerpen:
Physical Sciences
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939097/
https://ncbi.nlm.nih.gov/pubmed/29610304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1721717115
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