Structural characterization of a non-heme iron active site in zeolites that hydroxylates methane

Iron-containing zeolites exhibit unprecedented reactivity in the low-temperature hydroxylation of methane to form methanol. Reactivity occurs at a mononuclear ferrous active site, α-Fe(II), that is activated by N(2)O to form the reactive intermediate α-O. This has been defined as an Fe(IV)=O species...

Πλήρης περιγραφή

Αποθηκεύτηκε σε:
Λεπτομέρειες βιβλιογραφικής εγγραφής
Τόπος έκδοσης:Proc Natl Acad Sci U S A
Κύριοι συγγραφείς: Snyder, Benjamin E. R., Böttger, Lars H., Bols, Max L., Yan, James J., Rhoda, Hannah M., Jacobs, Ariel B., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.
Μορφή: Artigo
Γλώσσα:Inglês
Έκδοση: National Academy of Sciences 2018
Θέματα:
Physical Sciences
Διαθέσιμο Online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939097/
https://ncbi.nlm.nih.gov/pubmed/29610304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1721717115
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