Structural characterization of a non-heme iron active site in zeolites that hydroxylates methane

Iron-containing zeolites exhibit unprecedented reactivity in the low-temperature hydroxylation of methane to form methanol. Reactivity occurs at a mononuclear ferrous active site, α-Fe(II), that is activated by N(2)O to form the reactive intermediate α-O. This has been defined as an Fe(IV)=O species...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Snyder, Benjamin E. R., Böttger, Lars H., Bols, Max L., Yan, James J., Rhoda, Hannah M., Jacobs, Ariel B., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2018
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939097/
https://ncbi.nlm.nih.gov/pubmed/29610304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1721717115
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