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Benchmarking lithium amide versus amine bonding by charge density and energy decomposition analysis arguments

Lithium amides are versatile C–H metallation reagents with vast industrial demand because of their high basicity combined with their weak nucleophilicity, and they are applied in kilotons worldwide annually. The nuclearity of lithium amides, however, modifies and steers reactivity, region- and stere...

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Vydáno v:Chem Sci
Hlavní autoři: Engelhardt, Felix, Maaß, Christian, Andrada, Diego M., Herbst-Irmer, Regine, Stalke, Dietmar
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5916014/
https://ncbi.nlm.nih.gov/pubmed/29732094
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05368a
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