Insights into the Topology and the Formation of a Genuine ppσ Bond: Experimental and Computed Electron Densities in Monoanionic Trichlorine [Cl(3)](−)

So far, several publications have discussed the bonding concepts in polyhalides on a theoretical basis. In particular, the trichlorine monoanion is of great interest because its structure should be symmetrical and show two equidistant Cl−Cl bonds. However, apart from matrix‐isolation studies, only a...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Keil, Helena, Sonnenberg, Karsten, Müller, Carsten, Herbst‐Irmer, Regine, Beckers, Helmut, Riedel, Sebastian, Stalke, Dietmar
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898528/
https://ncbi.nlm.nih.gov/pubmed/33151006
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013727
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